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Properties of substance:

lithium chloride

Group of substances:

inorganic

Physical appearance:

colorless cubic crystals

Empirical formula (Hill's system for organic substances):

ClLi

Structural formula as text:

LiCl

Molar/atomic mass: 42.39

Melting point (°C):

614

Boiling point (°C):

1380

Solubility (g/100 g of solvent):

1-butanol: 12.98 (25°C) [Ref.]
1-pentanol: 7.19 (20°C) [Ref.]
1-pentanol: 9 (25°C) [Ref.]
1-propanol: 15.85 (20°C) [Ref.]
4-hydroxy-4-methyl-2-pentanone: 6.54 (20°C) [Ref.]
4-hydroxy-4-methyl-2-pentanone: 7.32 (35°C) [Ref.]
4-hydroxy-4-methyl-2-pentanone: 8.79 (50°C) [Ref.]
4-hydroxy-4-methyl-2-pentanone: 11.02 (65°C) [Ref.]
N-methylformamide: 23 (25°C) [Ref.]
acetone: 1.2 (20°C) [Ref.]
acetone: 1.08 (25°C) [Ref.]
acetone: 0.95 (30°C) [Ref.]
acetone: 0.73 (40°C) [Ref.]
acetone: 0.61 (50°C) [Ref.]
acetonitrile: 0.15 (18°C) [Ref.]
acetonitrile: 0.14 (25°C) [Ref.]
allyl alcohol: 4.37 (25°C) [Ref.]
ammonia liquid : 0.54 (-34°C) [Ref.]
ammonia liquid : 1.41 (0°C) [Ref.]
antimony trichloride: very slightly soluble [Ref.]
bromine liquid: 0.0037 (25°C) [Ref.]
chloroform: soluble [Ref.]
dimethylamine: soluble [Ref.]
dimethylformamide: 11 (28°C) [Ref.]
ethanol: 14.4 (0°C) [Ref.]
ethanol: 16.8 (10°C) [Ref.]
ethanol: 24.3 (20°C) [Ref.]
ethanol: 25.4 (40°C) [Ref.]
ethanol: 23.5 (60°C) [Ref.]
ethyl acetate: soluble [Ref.]
ethylene glycol : 14.3 (25°C) [Ref.]
ethylenediamine: 1.39 (25°C) [Ref.]
formamide: 28.2 (25°C) [Ref.]
formic acid: 26.6 (18°C) [Ref.]
formic acid: 27.5 (25°C) [Ref.]
glycerol: 11.1 (15°C) [Ref.]
hydrazine: 16 (20°C) [Ref.]
iodine monochloride: sparingly soluble [Ref.]
methanol: 45.2 (0°C) [Ref.]
methanol: 44.2 (10°C) [Ref.]
methanol: 44 (15°C) [Ref.]
methanol: 43.8 (20°C) [Ref.]
methanol: 43.8 (30°C) [Ref.]
methanol: 44.1 (40°C) [Ref.]
methanol: 44.4 (50°C) [Ref.]
methanol: 44.6 (60°C) [Ref.]
methylamine: very soluble [Ref.]
nickel tetracarbonyl: insoluble [Ref.]
phenol: 1.93 (53°C) [Ref.]
phosphorus(V) trichloride oxide: 0.003 (20°C) [Ref.]
propylene carbonate: 0.003 (25°C) [Ref.]
pyridine: 7.8 (15°C) [Ref.]
quinoline: 0.1517 (0°C) [Ref.]
quinoline: 0.355 (25°C) [Ref.]
quinoline: 1.2369 (67°C) [Ref.]
quinoline: 0.4584 (96°C) [Ref.]
selenium(IV) oxychloride: 3.32 (25°C) [Ref.]
sulfur dioxide: 0.012 (0°C) [Ref.]
tetrahydrofuran: 5.56 (25°C) [Ref.]
water: 68.3 (0°C) [Ref.]
water: 74.5 (10°C) [Ref.]
water: 83.2 (20°C) [Ref.]
water: 84.5 (25°C) [Ref.]
water: 85.9 (30°C) [Ref.]
water: 89.4 (40°C) [Ref.]
water: 98.8 (60°C) [Ref.]
water: 112.3 (80°C) [Ref.]
water: 128.8 (100°C) [Ref.]
water: 134.2 (125°C) [Ref.]
water: 139.7 (150°C) [Ref.]

Properties of solutions:

10% (wt.), solvent - water
  Dynamic viscosity (mPa·s) = 1.411 (20°)
  Density (g/cm3) = 1.056 (20°)
  Index of refraction = 1.3541 (20°)
  Freezing point (°C) = -12.61

Not numerical data:

hygroscopic

Density:

2.07 (25°C, g/cm3)

Vapour pressure (Torr):

0.1 (674°C)
1 (785°C)
10 (934°C)
100 (1130°C)

Viscosity (mPa·s):

1.59 (637°C)
1.21 (707°C)
0.87 (807°C)

Surface tension (mN/m):

128 (620°C)
127 (650°C)
124 (700°C)
123 (800°C)
114 (870°C)

Standard molar enthalpy (heat) of formation ΔfH0 (298.15 K, kJ/mol):

-408.3 (s)

Standard molar Gibbs energy of formation ΔfG0 (298.15 K, kJ/mol):

-384 (s)

Standard molar entropy S0 (298.15 K, J/(mol·K)):

59.3 (s)

Molar heat capacity at constant pressure Cp (298.15 K, J/(mol·K)):

48.03 (s)

Molar enthalpy (heat) of fusion ΔfusH (kJ/mol):

13.4

Enthalpy (heat) of vaporization ΔvapH (kJ/mol):

150.6

Standard molar enthalpy (heat) of formation ΔfH0 (298.15 K, kJ/mol):

-195 (g)

Standard molar entropy S0 (298.15 K, J/(mol·K)):

212.74 (g)

Molar heat capacity at constant pressure Cp (298.15 K, J/(mol·K)):

33.25 (g)

LD50 (mg/kg):

1170 (white mice, oral)
775 (rabbits, oral)
700 (rabbits, subcutaneous)
1530 (rats, oral)
925 (rats, intraperitoneal)
624 (guinea pig, intraperitoneal)
970 (mice, subcutaneous)
680 (mice, intraperitoneal)

References:

  1. Industrial and Engineering Chemistry Research. - 2010. - Vol. 49, No. 10. - pp. 4982
  2. Seidell A. Solubilities of inorganic and metal organic compounds. - 3ed., vol.1. - New York: D. Van Nostrand Company, 1940. - pp. 912-919
  3. Вредные вещества в промышленности: Справочник для химиков, инженеров и врачей. - 7-е изд., Т.3. - Л.: Химия, 1976. - pp. 321 [Russian]
  4. Вредные химические вещества: Неорганические соединения элементов I-IV групп. Справочник. - Л.: Химия, 1988. - pp. 26 [Russian]
  5. Рабинович В.А., Хавин З.Я. Краткий химический справочник. - Л.: Химия, 1977. - pp. 77 [Russian]
  6. Редкие и рассеянные элементы. Химия и технология. - Кн. 1. - М.: Мисис, 1996. - pp. 30-32 [Russian]
  7. Справочник по растворимости. - Т.1, Кн.1. - М.-Л.: ИАН СССР, 1961. - pp. 638-642, 738-739 [Russian]
  8. Фурман А.А. Неорганические хлориды (химия и технология). - М.: Химия, 1980. - pp. 26-33 [Russian]
  9. Химия и технология редких и рассеянных элементов. - Ч. 1. - М.: Высшая школа, 1976. - pp. 19-21 [Russian]

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    © Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru