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Properties of substance:
lithium chloride
Group of substances:
inorganic
Physical appearance:
colorless cubic crystals
Empirical formula (Hill's system for organic substances):
ClLi
Structural formula as text:
LiCl
Molar/atomic mass: 42.39
Melting point (°C):
614
Boiling point (°C):
1380
Solubility (g/100 g of solvent):
1-butanol
: 12.98 (25°C) [
Ref.
]
1-pentanol
: 7.19 (20°C) [
Ref.
]
1-pentanol
: 9 (25°C) [
Ref.
]
1-propanol
: 15.85 (20°C) [
Ref.
]
4-hydroxy-4-methyl-2-pentanone
: 6.54 (20°C) [
Ref.
]
4-hydroxy-4-methyl-2-pentanone
: 7.32 (35°C) [
Ref.
]
4-hydroxy-4-methyl-2-pentanone
: 8.79 (50°C) [
Ref.
]
4-hydroxy-4-methyl-2-pentanone
: 11.02 (65°C) [
Ref.
]
N-methylformamide
: 23 (25°C) [
Ref.
]
acetone
: 1.2 (20°C) [
Ref.
]
acetone
: 1.08 (25°C) [
Ref.
]
acetone
: 0.95 (30°C) [
Ref.
]
acetone
: 0.73 (40°C) [
Ref.
]
acetone
: 0.61 (50°C) [
Ref.
]
acetonitrile
: 0.15 (18°C) [
Ref.
]
acetonitrile
: 0.14 (25°C) [
Ref.
]
allyl alcohol
: 4.37 (25°C) [
Ref.
]
ammonia liquid
: 0.54 (-34°C) [
Ref.
]
ammonia liquid
: 1.41 (0°C) [
Ref.
]
antimony trichloride
: very slightly soluble [
Ref.
]
bromine liquid
: 0.0037 (25°C) [
Ref.
]
chloroform
: soluble [
Ref.
]
dimethylamine
: soluble [
Ref.
]
dimethylformamide
: 11 (28°C) [
Ref.
]
ethanol
: 14.4 (0°C) [
Ref.
]
ethanol
: 16.8 (10°C) [
Ref.
]
ethanol
: 24.3 (20°C) [
Ref.
]
ethanol
: 25.4 (40°C) [
Ref.
]
ethanol
: 23.5 (60°C) [
Ref.
]
ethyl acetate
: soluble [
Ref.
]
ethylene glycol
: 14.3 (25°C) [
Ref.
]
ethylenediamine
: 1.39 (25°C) [
Ref.
]
formamide
: 28.2 (25°C) [
Ref.
]
formic acid
: 26.6 (18°C) [
Ref.
]
formic acid
: 27.5 (25°C) [
Ref.
]
glycerol
: 11.1 (15°C) [
Ref.
]
hydrazine
: 16 (20°C) [
Ref.
]
iodine monochloride
: sparingly soluble [
Ref.
]
methanol
: 45.2 (0°C) [
Ref.
]
methanol
: 44.2 (10°C) [
Ref.
]
methanol
: 44 (15°C) [
Ref.
]
methanol
: 43.8 (20°C) [
Ref.
]
methanol
: 43.8 (30°C) [
Ref.
]
methanol
: 44.1 (40°C) [
Ref.
]
methanol
: 44.4 (50°C) [
Ref.
]
methanol
: 44.6 (60°C) [
Ref.
]
methylamine
: very soluble [
Ref.
]
nickel tetracarbonyl
: insoluble [
Ref.
]
phenol
: 1.93 (53°C) [
Ref.
]
phosphorus(V) trichloride oxide
: 0.003 (20°C) [
Ref.
]
propylene carbonate
: 0.003 (25°C) [
Ref.
]
pyridine
: 7.8 (15°C) [
Ref.
]
quinoline
: 0.1517 (0°C) [
Ref.
]
quinoline
: 0.355 (25°C) [
Ref.
]
quinoline
: 1.2369 (67°C) [
Ref.
]
quinoline
: 0.4584 (96°C) [
Ref.
]
selenium(IV) oxychloride
: 3.32 (25°C) [
Ref.
]
sulfur dioxide
: 0.012 (0°C) [
Ref.
]
tetrahydrofuran
: 5.56 (25°C) [
Ref.
]
water
: 68.3 (0°C) [
Ref.
]
water
: 74.5 (10°C) [
Ref.
]
water
: 83.2 (20°C) [
Ref.
]
water
: 84.5 (25°C) [
Ref.
]
water
: 85.9 (30°C) [
Ref.
]
water
: 89.4 (40°C) [
Ref.
]
water
: 98.8 (60°C) [
Ref.
]
water
: 112.3 (80°C) [
Ref.
]
water
: 128.8 (100°C) [
Ref.
]
water
: 134.2 (125°C) [
Ref.
]
water
: 139.7 (150°C) [
Ref.
]
Properties of solutions:
10% (wt.), solvent - water
Dynamic viscosity (mPa·s) = 1.411 (20°)
Density (g/cm
3
) = 1.056 (20°)
Index of refraction = 1.3541 (20°)
Freezing point (°C) = -12.61
Not numerical data:
hygroscopic
Density:
2.07 (25°C, g/cm
3
)
Vapour pressure (Torr):
0.1 (674°C)
1 (785°C)
10 (934°C)
100 (1130°C)
Viscosity (mPa·s):
1.59 (637°C)
1.21 (707°C)
0.87 (807°C)
Surface tension (mN/m):
128 (620°C)
127 (650°C)
124 (700°C)
123 (800°C)
114 (870°C)
Standard molar enthalpy (heat) of formation Δ
f
H
0
(298.15 K, kJ/mol):
-408.3 (s)
Standard molar Gibbs energy of formation Δ
f
G
0
(298.15 K, kJ/mol):
-384 (s)
Standard molar entropy S
0
(298.15 K, J/(mol·K)):
59.3 (s)
Molar heat capacity at constant pressure C
p
(298.15 K, J/(mol·K)):
48.03 (s)
Molar enthalpy (heat) of fusion Δ
fus
H (kJ/mol):
13.4
Enthalpy (heat) of vaporization Δ
vap
H (kJ/mol):
150.6
Standard molar enthalpy (heat) of formation Δ
f
H
0
(298.15 K, kJ/mol):
-195 (g)
Standard molar entropy S
0
(298.15 K, J/(mol·K)):
212.74 (g)
Molar heat capacity at constant pressure C
p
(298.15 K, J/(mol·K)):
33.25 (g)
LD
50
(mg/kg):
1170 (white mice, oral)
775 (rabbits, oral)
700 (rabbits, subcutaneous)
1530 (rats, oral)
925 (rats, intraperitoneal)
624 (guinea pig, intraperitoneal)
970 (mice, subcutaneous)
680 (mice, intraperitoneal)
References:
Industrial and Engineering Chemistry Research. - 2010. - Vol. 49, No. 10. - pp. 4982
Seidell A. Solubilities of inorganic and metal organic compounds. - 3ed., vol.1. - New York: D. Van Nostrand Company, 1940. - pp. 912-919
Вредные вещества в промышленности: Справочник для химиков, инженеров и врачей. - 7-е изд., Т.3. - Л.: Химия, 1976. - pp. 321 [Russian]
Вредные химические вещества: Неорганические соединения элементов I-IV групп. Справочник. - Л.: Химия, 1988. - pp. 26 [Russian]
Рабинович В.А., Хавин З.Я. Краткий химический справочник. - Л.: Химия, 1977. - pp. 77 [Russian]
Редкие и рассеянные элементы. Химия и технология. - Кн. 1. - М.: Мисис, 1996. - pp. 30-32 [Russian]
Справочник по растворимости. - Т.1, Кн.1. - М.-Л.: ИАН СССР, 1961. - pp. 638-642, 738-739 [Russian]
Фурман А.А. Неорганические хлориды (химия и технология). - М.: Химия, 1980. - pp. 26-33 [Russian]
Химия и технология редких и рассеянных элементов. - Ч. 1. - М.: Высшая школа, 1976. - pp. 19-21 [Russian]
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© Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru