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Properties of substance:
fluorodiazonium hexafluoroarsenate
Group of substances:
inorganic
Physical appearance:
colorless crystals
Empirical formula (Hill's system for organic substances):
AsF
7
N
2
Structural formula as text:
N2F(AsF6)
Molar/atomic mass: 235.92
Decomposition temperature (°C):
150
Solubility (g/100 g of solvent):
bromine trifluoride
: reaction [
Ref.
]
chlorine trifluoride
: reaction [
Ref.
]
hydrogen fluoride
: soluble [
Ref.
]
water
: reaction [
Ref.
]
Density:
2.6 (25°C, g/cm
3
)
Reactions of synthesis:
[
Ref.1
]
N
2
F
2
+ AsF
5
→ N
2
F[AsF
6
]
Reactions:
[
Ref.1
]
NOCl + N
2
F[AsF
6
] → NOClF[AsF
6
] + N
2
[
Ref.1
]
N
2
F[AsF
6
] + ClF → ClF
2
[AsF
6
] + N
2
[
Ref.1
]
N
2
F[AsF
6
] + Xe → XeF[AsF
6
] + N
2
[
Ref.1
]
N
2
F[AsF
6
] + AgClO
4
→ Ag[AsF
6
] + N
2
O + ClO
3
F
References:
Journal of the American Chemical Society. - 1965. - Vol. 87, No. 9. - pp. 1889-1892 [DOI:
10.1021/ja01087a010
]
Journal of the American Chemical Society. - 1991. - Vol. 113, No. 10. - pp. 3795-3800 [DOI:
10.1021/ja00010a023
]
Journal of the American Chemical Society. - 1994. - Vol. 116, No. 13. - pp. 5671-5673
Некрасов Б.В. Основы общей химии. - Т.1. - М.: Химия, 1973. - pp. 476-477 [Russian]
Панкратов А.В. Химия фторидов азота. - М.: Химия, 1973. - pp. 219 [Russian]
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© Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru