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Properties of substance:

fluorodiazonium hexafluoroarsenate

Group of substances:

inorganic

Physical appearance:

colorless crystals

Empirical formula (Hill's system for organic substances):

AsF7N2

Structural formula as text:

N2F(AsF6)

Molar/atomic mass: 235.92

Decomposition temperature (°C):

150

Solubility (g/100 g of solvent):

bromine trifluoride: reaction [Ref.]
chlorine trifluoride: reaction [Ref.]
hydrogen fluoride : soluble [Ref.]
water: reaction [Ref.]

Density:

2.6 (25°C, g/cm3)

Reactions of synthesis:

  1. [Ref.1aster]
    N2F2 + AsF5 → N2F[AsF6]

Reactions:

  1. [Ref.1]
    NOCl + N2F[AsF6] → NOClF[AsF6] + N2
  2. [Ref.1]
    N2F[AsF6] + ClF → ClF2[AsF6] + N2
  3. [Ref.1]
    N2F[AsF6] + Xe → XeF[AsF6] + N2
  4. [Ref.1]
    N2F[AsF6] + AgClO4 → Ag[AsF6] + N2O + ClO3F

References:

  1. Journal of the American Chemical Society. - 1965. - Vol. 87, No. 9. - pp. 1889-1892 [DOI: 10.1021/ja01087a010]
  2. Journal of the American Chemical Society. - 1991. - Vol. 113, No. 10. - pp. 3795-3800 [DOI: 10.1021/ja00010a023]
  3. Journal of the American Chemical Society. - 1994. - Vol. 116, No. 13. - pp. 5671-5673
  4. Некрасов Б.В. Основы общей химии. - Т.1. - М.: Химия, 1973. - pp. 476-477 [Russian]
  5. Панкратов А.В. Химия фторидов азота. - М.: Химия, 1973. - pp. 219 [Russian]

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    © Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru