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Properties of substance:
sodium acetate
Group of substances:
inorganic
Physical appearance:
colorless monoclinic crystals
Empirical formula (Hill's system for organic substances):
C
2
H
3
NaO
2
Structural formula as text:
CH3COONa
Molar/atomic mass: 82.03
Melting point (°C):
328.1
Solubility (g/100 g of solvent):
1-propanol
: 0.97 (20°C) [
Ref.
]
1-propanol
: 1.1 (25°C) [
Ref.
]
acetic acid
: 10.46 (25.3°C) [
Ref.
]
acetic acid
: 67.79 (96.3°C) [
Ref.
]
acetone
: 0.05 (15°C) [
Ref.
]
acetonitrile
: 0.014 (25°C) [
Ref.
]
diethyl ether
: slightly soluble [
Ref.
]
ethanol
: slightly soluble [
Ref.
]
ethanol 98.4%
: 2.08 (8°C) [
Ref.
]
ethanol 98.4%
: 2.33 (19°C) [
Ref.
]
ethyl acetate
: insoluble [
Ref.
]
ethylene glycol
: 29.03 (25°C) [
Ref.
]
formic acid
: 23.92 (-18.2°C) [
Ref.
]
formic acid
: 7.76 (0.9°C) [
Ref.
]
hydrazine
: 6 (20°C) [
Ref.
]
methanol
: 16 (15°C) [
Ref.
]
methanol
: 17.42 (25°C) [
Ref.
]
methanol
: 16.55 (67.7°C) [
Ref.
]
sulfur dioxide
: 0.073 (0°C) [
Ref.
]
water
: 36.3 (0°C) [
Ref.
]
water
: 40.8 (10°C) [
Ref.
]
water
: 46.5 (20°C) [
Ref.
]
water
: 61.55 (25°C) [
Ref.
]
water
: 54.5 (30°C) [
Ref.
]
water
: 65.5 (40°C) [
Ref.
]
water
: 83 (50°C) [
Ref.
]
water
: 138 (58°C) [
Ref.
]
water
: 139.5 (60°C) [
Ref.
]
water
: 146 (70°C) [
Ref.
]
water
: 153 (80°C) [
Ref.
]
water
: 161 (90°C) [
Ref.
]
water
: 170 (100°C) [
Ref.
]
water
: 180 (110°C) [
Ref.
]
water
: 191 (120°C) [
Ref.
]
water
: 193 (123°C) [
Ref.
]
Properties of solutions:
9% (wt.), solvent - water
Dynamic viscosity (mPa·s) = 1.468 (20°)
Density (g/cm
3
) = 1.044 (20°)
Index of refraction = 1.3456 (20°)
Freezing point (°C) = -4.57
20,57% (wt.), solvent - water
Freezing point (°C) = -15.17
Density:
1.528 (20°C, g/cm
3
)
Reactions:
Yeild 29%. [
Ref.1
]
CH
3
COONa + CH
3
CH
2
CH
2
CH
2
Cl → CH
3
COOCH
2
CH
2
CH
2
CH
3
+ NaCl
Yeild 96%. [
Ref.1
]
CH
3
COONa + CH
3
CH
2
CH
2
CH
2
Br → CH
3
COOCH
2
CH
2
CH
2
CH
3
+ NaBr
Yeild 85%. [
Ref.1
]
AlCl
3
* 6H
2
O + 3CH
3
COONa → (CH
3
COO)
2
AlOH + 3NaCl + CH
3
COOH + 5H
2
O
[
Ref.1
,
Ref.2
]
CH
3
COONa + NaOH → CH
4
+ Na
2
CO
3
Dissociation:
pK
a
(1) = 24 (20°C, water)
Standard molar enthalpy (heat) of formation Δ
f
H (298 K, kJ/mol)
-708.8 (s) [
Ref.
]
Standard molar Gibbs energy of formation Δ
f
G (298 K, kJ/mol)
-607.2 (s) [
Ref.
]
Standard molar entropy S (298 K, J/(mol·K))
123 (s) [
Ref.
]
Molar heat capacity at constant pressure C
p
(298 K, J/(mol·K))
79.9 (s) [
Ref.
]
Enthalpy (heat) of fusion Δ
fus
H (kJ/mol)
17.9 (s) [
Ref.
]
Uses:
drug: diuretic [
Ref.
]
References:
Indian Journal of Chemistry. Section A. - 2005. - Vol. 44, No. 8. - pp. 1595
Seidell A. Solubilities of inorganic and metal organic compounds. - 3ed., vol.1. - New York: D. Van Nostrand Company, 1940. - pp. 1167-1169
Гордон А., Форд Р. Спутник химика. - М.: Мир, 1976. - pp. 77 [Russian]
Краткий справочник по химии. - Под ред. Куриленко О.Д. - Киев: Наукова думка, 1974. - pp. 489 [Russian]
Лурье Ю.Ю. Справочник по аналитической химии. - М.: Химия, 1979. - pp. 78-79 [Russian]
Рабинович В.А., Хавин З.Я. Краткий химический справочник. - Л.: Химия, 1977. - pp. 83 [Russian]
Справочник по растворимости. - Т.1, Кн.1. - М.-Л.: ИАН СССР, 1961. - pp. 673-674, 677 [Russian]
Справочник химика. - Т. 2. - Л.-М.: Химия, 1964. - pp. 144-145 [Russian]
Справочник химика. - Т. 3. - М.-Л.: Химия, 1965. - pp. 211, 290, 302 [Russian]
Химическая энциклопедия. - Т. 3. - М.: Советская энциклопедия, 1992. - pp. 180 [Russian]
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© Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru