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Properties of substance:
manganese(VII) oxide
Group of substances:
inorganic
Physical appearance:
deep-green oily liquid
Empirical formula (Hill's system for organic substances):
Mn
2
O
7
Structural formula as text:
Mn2O7
Molar/atomic mass: 221.87
Melting point (°C):
5.9
Decomposition temperature (°C):
55
CAS №: 12057-92-0
Solubility (g/100 g of solvent):
acetic anhydride
: soluble [
Ref.
]
acetone
: ignites [
Ref.
]
ethanol
: ignites [
Ref.
]
water
: reaction [
Ref.
]
Density:
2.396 (20°C, d
4
)
Reactions of synthesis:
[
Ref.1
,
Ref.2
]
2KMnO
4
+ H
2
SO
4
→ Mn
2
O
7
+ K
2
SO
4
+ H
2
O
Permittivity (dielectric constant):
3.28 (20°C)
3.3 (11°C)
3.27 (30°C)
3.25 (39°C)
Standard molar enthalpy (heat) of formation Δ
f
H
0
(298.15 K, kJ/mol):
-726.3 (l)
References:
Bretherick's Handbook of Reactive Chemical Hazards. - 6 ed., Vol. 1. - Butterworth-Heinemann, 1999. - pp. 1770
CRC Handbook of Chemistry and Physics. - 90ed. - CRC Press, 2010. - pp. 4-75, 6-149
Zeitschrift fur anorganische und allgemeine Chemie. - 1953. - Vol. 271, No. 5-6. - pp. 293-304
Некрасов Б.В. Основы общей химии. - Т.1. - М.: Химия, 1973. - pp. 307 [Russian]
Неорганическая химия. – Под ред. Третьякова Ю.Д., Т.3, Кн.1. - М.: Академия, 2007. - pp. 286-287 [Russian]
Позин М.Е. Технология минеральных солей (удобрений, пестицидов, промышленных солей, окислов и кислот). - Ч.1. - Л.: Химия, 1974. - pp. 756 [Russian]
Рабинович В.А., Хавин З.Я. Краткий химический справочник. - Л.: Химия, 1977. - pp. 79 [Russian]
Химическая энциклопедия. - Т. 2. - М.: Советская энциклопедия, 1990. - pp. 650 [Russian]
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© Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru