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Properties of substance:

sodium paraperiodate

Group of substances:

inorganic

Physical appearance:

white crystals

Empirical formula (Hill's system for organic substances):

H2INa3O6

Structural formula as text:

Na3H2IO6

Molar/atomic mass: 293.89

Melting point (°C):

200

Decomposition temperature (°C):

200

Reactions of synthesis:

  1. [Ref.1]
    H5IO6 + 3NaOH → Na3H2IO6 + 3H2O
  2. Yeild 93-98%. [Ref.1aster]
    NaI + 4Br2 + 10NaOH → Na3H2IO6 + 8NaBr + 4H2O
  3. [Ref.1aster]
    NaIO3 + 4NaOH + Cl2 → Na3H3IO6 + 2NaCl + H2O
  4. [Ref.1aster]
    NaIO3 + 4NaOH + K2S2O8 → Na3H3IO6 + K2SO4 + Na2SO4 + H2O

Reactions:

  1. [Ref.1aster]
    Na3H2IO6 + 2HNO3 → NaIO4 + 2NaNO3 + 2H2O

References:

  1. Inorganic Syntheses. - Vol. 1. - New York and London, 1939. - pp. 168-170
  2. Лидин Р.А., Андреева Л.Л., Молочко В.А. Константы неорганических веществ. - М.: Дрофа, 2006. - pp. 138 [Russian]
  3. Химический энциклопедический словарь. - Под ред. Кнунянц И.Л. - М.: Советская энциклопедия, 1983. - pp. 362 [Russian]

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    © Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru