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Properties of substance:

dimanganese decacarbonyl

Group of substances:

inorganic

Physical appearance:

crystals

Empirical formula (Hill's system for organic substances):

C10Mn2O10

Structural formula as text:

Mn2(CO)10

Molar/atomic mass: 389.977

Melting point (°C):

155

Decomposition temperature (°C):

110

Solubility (g/100 g of solvent):

tetrahydrofuran: very soluble [Ref.]
water: insoluble [Ref.]

Numerical data:

Year of discovery: 1949

Density:

1.75 (20°C, g/cm3)

Electrode potential:

Mn2(CO)10 + 2e- → 2Mn(CO)5-, E = -0.68 V (water, 25°C)

Standard molar enthalpy (heat) of formation ΔfH0 (298.15 K, kJ/mol):

-1676 (s)

References:

  1. CRC Handbook of Chemistry and Physics. - 95ed. - CRC Press, 2014. - pp. 3-342
  2. Holleman A.F., Wiberg E., Wiberg N. Lehrbuch der Anorganischen Chemie. - Berlin: Walter de Gruyter, 1995. - pp. 1631, 1648
  3. Белозерский Н.А. Карбонилы металлов. - М.: ГНТИЛЧЦМ, 1958. - pp. 302-303 [Russian]
  4. Гринвуд Н., Эрншо А. Химия элементов. - Т.2. - М.: БИНОМ. Лаборатория знаний, 2008. - pp. 392-394 [Russian]
  5. Некрасов Б.В. Основы общей химии. - Т.1. - М.: Химия, 1973. - pp. 516 [Russian]
  6. Синтезы неорганических соединений. - Т.1, под ред. Джолли У. - М.: Мир, 1966. - pp. 117 [Russian]
  7. Успехи химии. - 1968. - Т.37, №3. - pp. 380-408 [Russian]
  8. Химическая энциклопедия. - Т. 2. - М.: Советская энциклопедия, 1990. - pp. 649 [Russian]

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    © Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru