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Properties of substance:
propenenitrile
Synonyms:
acrylonitrile
Group of substances:
organic
Physical appearance:
colorless liquid
Empirical formula (Hill's system for organic substances):
C
3
H
3
N
Structural formula as text:
CH2=CHCN
Molar/atomic mass: 53.06
Melting point (°C):
-82
Boiling point (°C):
79
Solubility (g/100 g of solvent):
acetone
: very soluble [
Ref.
]
benzene
: very soluble [
Ref.
]
diethyl ether
: miscible [
Ref.
]
ethanol
: miscible [
Ref.
]
sulfolane
: miscible [
Ref.
]
water
: 6.716 (0°C) [
Ref.
]
water
: 6.803 (20°C) [
Ref.
]
water
: 8.173 (59°C) [
Ref.
]
water
: 11.27 (90°C) [
Ref.
]
Density:
0.797 (20°C, d
4
)
Reactions:
Yeild 71%. [
Ref.1
]
C
6
H
5
NH
2
+ (CH
3
)
3
CONO + CH
2
=CHCN + CuCl
2
→ C
6
H
5
CH
2
CHClCN + N
2
+ Cu(OH)Cl + (CH
3
)
3
COH
Standard molar enthalpy (heat) of formation Δ
f
H
0
(298.15 K, kJ/mol):
147.1 (l)
Standard molar enthalpy (heat) of formation Δ
f
H
0
(298.15 K, kJ/mol):
180.6 (g)
LD
50
(mg/kg):
93-100 (rabbits, oral)
50 (guinea pig, oral)
20 (mice, oral)
References:
CRC Handbook of Chemistry and Physics. - 90ed. - CRC Press, 2010. - pp. 5-23
Gangolli S. The Dictionary of Substances and their Effects. - 2 ed., Vol. 1, A-B. - RSC, 1999. - pp. 74-78
Lewis R.J. Sax's Dangerous Properties of Industrial Materials. - 11ed. - Wiley-interscience, 2004. - pp. 72-73
Milne G.W.A. Gardner's Commercially Important Chemicals. - Wiley-Interscience, 2005. - pp. 12
Yalkowsky S.H., Yan H., Jain P. Handbook of aqueous solubility data. – 2nd ed. - CRC Press, 2010. - pp. 46
Вредные вещества в промышленности: Справочник для химиков, инженеров и врачей. - 7-е изд., Т.2. - Л.: Химия, 1976. - pp. 105-108 [Russian]
Справочник химика. - Т. 2. - Л.-М.: Химия, 1964. - pp. 406-407 [Russian]
Химический энциклопедический словарь. - Под ред. Кнунянц И.Л. - М.: Советская энциклопедия, 1983. - pp. 17 [Russian]
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© Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru
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