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Properties of substance:
californium
Group of substances:
inorganic
Physical appearance:
metal
Empirical formula (Hill's system for organic substances):
Cf
Structural formula as text:
Cf
Molar/atomic mass: 251
Melting point (°C):
900
Boiling point (°C):
1227
Numerical data:
Year of discovery: 195
Half-life:
238
98
Cf = 21.1 ms (spontaneous fission (about 100%))
239
98
Cf = 60 s ()
240
98
Cf = 1.06 min (spontaneous fission (about 98%), α (about 2%))
241
98
Cf = 3.8 min (β
+
(about 75%), α (about 25%))
242
98
Cf = 3.49 min (α (about 80%))
243
98
Cf = 10.7 min (β
+
(about 86%), α (about 14%))
244
98
Cf = 19.4 min (α (about 100%))
245
98
Cf = 45 min (β
+
(64%), α (36%))
246
98
Cf = 35.7 h (α (about 100%))
247
98
Cf = 3.11 h (electron capture (about 100%), α (0.035%))
248
98
Cf = 334 d (α (about 100%), spontaneous fission (0.0029%))
249
98
Cf = 351 y (α (about 100%), spontaneous fission (0.0000005%))
250
98
Cf = 13.08 y (α (about 100%), spontaneous fission (0.077%))
251
98
Cf = 900 y (α (about 100%))
252
98
Cf = 2.645 y (α (96.908%), spontaneous fission (3.092%))
253
98
Cf = 17.81 d (β
-
(about 100%), α (0.31%))
254
98
Cf = 60.5 d (spontaneous fission (about 100%), α (0.31%))
255
98
Cf = 85 min (β
-
(about 100%))
256
98
Cf = 12.3 min (spontaneous fission (about 100%))
Electrode potential:
Cf
3+
+ 3e
-
→ Cf, E = -1.91 V (water, 25°C)
Cf
4+
+ e
-
→ Cf
3+
, E = 3.1 V (water, 25°C)
Standard molar enthalpy (heat) of formation Δ
f
H
0
(298.15 K, kJ/mol):
0 (s)
Standard molar Gibbs energy of formation Δ
f
G
0
(298.15 K, kJ/mol):
0 (s)
Standard molar entropy S
0
(298.15 K, J/(mol·K)):
77 (s)
Molar heat capacity at constant pressure C
p
(298.15 K, J/(mol·K)):
29 (s)
ΔH
sublimation
(kJ/mol):
163
References:
Бекман И.Н. Радиохимия. Том II: Радиоактивные элементы. - М.: Издатель Мархитин П.Ю., 2014. - pp. 356-360 [Russian]
Вредные химические вещества: Радиоактивные вещества. Справочник. - Л., 1990. - pp. 224-225 [Russian]
Химическая энциклопедия. - Т. 2. - М.: Советская энциклопедия, 1990. - pp. 286-287 [Russian]
Химия актиноидов. - Т.2. - М.: Мир, 1997. - pp. 558-574 [Russian]
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© Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru