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Properties of substance:
iodoform
Synonyms:
triiodomethane
Group of substances:
organic
Physical appearance:
yellow hexagonal crystals
Empirical formula (Hill's system for organic substances):
CHI
3
Structural formula as text:
CHI3
Molar/atomic mass: 393.72
Melting point (°C):
123
Sublimation point (°C):
210
CAS №: 75-47-8
Solubility (g/100 g of solvent):
1,1,2-trichloro-1,2,2-trifluoroethane
: sparingly soluble [
Ref.
]
acetic acid
: soluble [
Ref.
]
acetone
: soluble [
Ref.
]
benzene
: insoluble [
Ref.
]
carbon disulphide
: soluble [
Ref.
]
chloroform
: soluble [
Ref.
]
diethyl ether
: 13.6 (25°C) [
Ref.
]
dimethylsulfoxide
: sparingly soluble [
Ref.
]
ethanol
: 1.3 (18°C) [
Ref.
]
ethanol
: 7.8 (78°C) [
Ref.
]
glycerol 95%
: 0.123 (15°C) [
Ref.
]
iodine liquid
: soluble [
Ref.
]
oils: sparingly soluble [
Ref.
]
water
: 0.01181 (25°C) [
Ref.
]
Not numerical data:
volatile in steam
Density:
4.008 (20°C, d
4
)
Vapour pressure (Torr):
0.0075 (51.1°C)
0.075 (82.7°C)
0.75 (121°C)
750 (218°C)
Dipole moment (D):
1 (20°C)
Standard molar enthalpy (heat) of formation Δ
f
H (298 K, kJ/mol)
-181.1 (s) [
Ref.
]
251 (g) [
Ref.
]
Standard molar entropy S (298 K, J/(mol·K))
356.2 (g) [
Ref.
]
Molar heat capacity at constant pressure C
p
(298 K, J/(mol·K))
75 (g) [
Ref.
]
Enthalpy (heat) of fusion Δ
fus
H (kJ/mol)
16.44 (s) [
Ref.
]
References:
CRC Handbook of Chemistry and Physics. - 90ed. - CRC Press, 2010. - pp. 5-19
CRC Handbook of Chemistry and Physics. - 95ed. - CRC Press, 2014. - pp. 3-530
Dictionary of Inorganic Compounds. - Vol. 1: Ac-C10, part 1. - Springer Science+Business Media Dordrecht, 1992. - pp. 415
Seidell A. Solubilities of organic compounds. - 3ed., vol.2. - New York: D. Van Nostrand Company, 1941. - pp. 21-22
Yalkowsky S.H., Yan H. Handbook of aqueous solubility data. - CRC Press, 2003. - pp. 5
Беликов В.Г. Учебное пособие по фармацевтической химии. - М.: Медицина, 1979. - pp. 95 [Russian]
Краткая химическая энциклопедия. - Т. 2: Ж-Малоновый эфир. - М.: Советская энциклопедия, 1963. - pp. 292-293 [Russian]
Некрасов Б.В. Основы общей химии. - Т.1. - М.: Химия, 1973. - pp. 553 [Russian]
Рабинович В.А., Хавин З.Я. Краткий химический справочник. - Л.: Химия, 1977. - pp. 151 [Russian]
Справочник по растворимости. - Т.1, Кн.2. - М.-Л.: ИАН СССР, 1962. - pp. 1106-1107 [Russian]
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© Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru