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Properties of substance:

manganese

Group of substances:

inorganic

Physical appearance:

cubic metal

Empirical formula (Hill's system for organic substances):

Mn

Structural formula as text:

Mn

Molar/atomic mass: 54.94

Melting point (°C):

1245

Boiling point (°C):

2080

Solubility (g/100 g of solvent):

hydrazine: insoluble [Ref.]
magnesium fused: 2.15 (670°C) [Ref.]
magnesium fused: 2.65 (710°C) [Ref.]
magnesium fused: 3.21 (760°C) [Ref.]
magnesium fused: 5.21 (850°C) [Ref.]
mercury: 0.00025 (18°C) [Ref.]
water: insoluble [Ref.]

Numerical data:

Year of discovery: 1774
Hardness on the Mohs’ scale: 5

Density:

7.44 (20°C, g/cm3)

Half-life:

4625Mn = 36.2 ms (β+ (100%), β-p (57%))
4725Mn = 88.0 ms (β+ (100%))
4825Mn = 158.1 ms (β+ (100%), β+p (0.28%))
4925Mn = 382 ms (β+ (100%))
5025Mn = 283.19 ms (β+ (100%))
50m25Mn = 1.75 min (β+ (100%))
5125Mn = 46.2 min (β+ (100%))
5225Mn = 5.591 d (β+ (100%))
52m25Mn = 21.1 min (β+ (98.25%), internal transition (1.25%))
5325Mn = 3 700 000 y (electron capture (100%))
5425Mn = 312.05 d (electron capture (100%))
5525Mn = stable ( (isotopic abundance 100%))
5625Mn = 2.5789 hasа (β- (100%))
5725Mn = 85.4 s (β- (100%))
5825Mn = 3.0 s (β- (100%))
5925Mn = 4.59 s (β- (100%))
6025Mn = 280 ms (β- (100%))
60m25Mn = 1.77 s (β- (88.5%), internal transition (11.5%))
6125Mn = 670 ms (β- (100%))
6225Mn = 92 ms (β- (100%))
62m25Mn = 671 ms (β- (100%))
6325Mn = 275 ms (β- (100%))
6425Mn = 88.8 ms (β- (100%), β-n (33%))
64m25Mn = 439 μs (internal transition (100%))
6525Mn = 62 ms (β- (100%))
6625Mn = 64.2 ms (β- (100%), β-n (8.4%))
66m25Mn = 780 μs (internal transition (about 100%))
6725Mn = 46.7 ms (β- (100%), β-n (10%))
6825Mn = 28.4 ms (β- (100%), β-n)
6925Mn = 16.0 ms (β- (100%), β-n)

Vapour pressure (Torr):

0.01 (974°C)
0.1 (1096°C)
1 (1219°C)
10 (1462°C)
100 (1745°C)

Electrode potential:

Mn2+ + 2e- → Mn, E = -1.179 V (water, 25°C)

Standard molar enthalpy (heat) of formation ΔfH0 (298.15 K, kJ/mol):

0 (s)

Standard molar Gibbs energy of formation ΔfG0 (298.15 K, kJ/mol):

0 (s)

Standard molar entropy S0 (298.15 K, J/(mol·K)):

32 (s)

Molar heat capacity at constant pressure Cp (298.15 K, J/(mol·K)):

26.3 (s)

Molar enthalpy (heat) of fusion ΔfusH (kJ/mol):

12

Enthalpy (heat) of vaporization ΔvapH (kJ/mol):

227

Neel temperature (K):

100

References:

  1. Гурвич Я.А. Справочник молодого аппаратчика-химика. - М.: Химия, 1991. - pp. 51 [Russian]
  2. Лаврухина А.К., Юкина Л.В. Аналитическая химия марганца. - М.: Наука, 1974. - pp. 11-15 [Russian]
  3. Неорганические синтезы. - Сб. 1. - М.: ИИЛ, 1951. - pp. 10 [Russian]
  4. Рабинович В.А., Хавин З.Я. Краткий химический справочник. - Л.: Химия, 1977. - pp. 78-79 [Russian]
  5. Справочник по растворимости. - Т.1, Кн.1. - М.-Л.: ИАН СССР, 1961. - pp. 636 [Russian]

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    © Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru