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Properties of substance:
acetoxime
Synonyms:
acetone oxime
Group of substances:
organic
Physical appearance:
colorless prismatic crystals
Empirical formula (Hill's system for organic substances):
C
3
H
7
NO
Structural formula as text:
(CH3)2C=NOH
Molar/atomic mass: 73.1
Melting point (°C):
61
Boiling point (°C):
136.3
Solubility (g/100 g of solvent):
diethyl ether
: very soluble [
Ref.
]
ethanol
: very soluble [
Ref.
]
ligroin: soluble [
Ref.
]
water
: very soluble [
Ref.
]
Density:
0.97 (20°C, g/cm
3
)
Reactions:
Yeild 25%. [
Ref.1
]
4(CH
3
)
2
C=NOH + 3N
2
O
4
→ 4(CH
3
)
2
C(NO)NO
2
+ 2H
2
O + 2NO
Yeild 90%. [
Ref.1
]
(CH
3
)
2
C=NOH + SO
2
→ NH
2
SO
3
H + (CH
3
)
2
CO
[
Ref.1
]
(CH
3
)
2
C=NOH + Br
2
→ (CH
3
)
2
CBrNO + HBr
Dissociation:
pK
a
(1) = 12.42 (25°C, water)
LD
50
(mg/kg):
4000 (mice, intraperitoneal)
References:
Dictionary of organic compounds. - vol.1, Abietic acid - Dypnone. - London, 1946. - pp. 13
Lewis R.J. Sax's Dangerous Properties of Industrial Materials. - 11ed. - Wiley-interscience, 2004. - pp. 24-25
Справочник химика. - Т. 2. - Л.-М.: Химия, 1964. - pp. 460-461 [Russian]
Химический энциклопедический словарь. - Под ред. Кнунянц И.Л. - М.: Советская энциклопедия, 1983. - pp. 63 [Russian]
Хмельницкий Л.И., Новиков С.С., Годовикова Т.И. Химия фуроксанов: строение и синтез. - М.: Наука, 1996. - pp. 199 [Russian]
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© Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru