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Properties of substance:
boron nitride
Group of substances:
inorganic
Physical appearance:
colorless hexagonal crystals
Empirical formula (Hill's system for organic substances):
BN
Structural formula as text:
BN
Molar/atomic mass: 24.82
Melting point (°C):
3000
Solubility (g/100 g of solvent):
hydrazine
: insoluble [
Ref.
]
water
: insoluble [
Ref.
]
Numerical data:
Vickers hardness (GPa): 62
Density:
2.34 (20°C, g/cm
3
)
Reactions of synthesis:
[
Ref.1
]
4BF
3
* NH
3
→ 3NH
4
BF
4
+ BN
Reactions:
Yeild 30%. [
Ref.1
]
BN + 3IF → NI
3
+ BF
3
Standard molar enthalpy (heat) of formation Δ
f
H
0
(298.15 K, kJ/mol):
-252.6 (s)
Standard molar Gibbs energy of formation Δ
f
G
0
(298.15 K, kJ/mol):
-226.8 (s)
Standard molar entropy S
0
(298.15 K, J/(mol·K)):
14.8 (s)
Molar heat capacity at constant pressure C
p
(298.15 K, J/(mol·K)):
19.7 (s)
References:
Гринвуд Н., Эрншо А. Химия элементов. - Т.1. - М.: БИНОМ. Лаборатория знаний, 2008. - pp. 199 [Russian]
Некрасов Б.В. Основы общей химии. - Т.2. - М.: Химия, 1973. - pp. 13-14 [Russian]
Рабинович В.А., Хавин З.Я. Краткий химический справочник. - Л.: Химия, 1977. - pp. 56 [Russian]
Самсонов Г.В. Нитриды. – Киев: Наукова думка, 1969. - pp. 231-259 [Russian]
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© Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru