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Properties of substance:
aluminum hydroxide α-form
Synonyms:
aluminium hydroxide α-form
Group of substances:
inorganic
Physical appearance:
colorless monoclinic crystals
Empirical formula (Hill's system for organic substances):
H
3
AlO
3
Structural formula as text:
Al(OH)3
Molar/atomic mass: 78.004
Decomposition temperature (°C):
150
Solubility (g/100 g of solvent):
water
: insoluble [
Ref.
]
Reactions:
[
Ref.1
]
Al(OH)
3
+ 3KHC
2
O
4
→ K
3
[Al(C
2
O
4
)
3
]*3H
2
O
[
Ref.1
]
Al(OH)
3
+ 2CH
3
COOH → (CH
3
COO)
2
AlOH + 2H
2
O
Electrode potential:
Al(OH)
3
+ 3e
-
→ Al + 3OH
-
, E = -2.31 V (water, 25°C)
Dissociation:
pK
b
(3) = 8.86 (25°C, water)
pK
sp
(0) = 32.3 (18°C, water)
Standard molar enthalpy (heat) of formation Δ
f
H
0
(298.15 K, kJ/mol):
-1315 (s)
Standard molar Gibbs energy of formation Δ
f
G
0
(298.15 K, kJ/mol):
-1157 (s)
Standard molar entropy S
0
(298.15 K, J/(mol·K)):
70.1 (s)
Molar heat capacity at constant pressure C
p
(298.15 K, J/(mol·K)):
93.07 (s)
References:
Гринвуд Н., Эрншо А. Химия элементов. - Т.1. - М.: БИНОМ. Лаборатория знаний, 2008. - pp. 231-233 [Russian]
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© Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru