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Properties of substance:
1-chloro-4-nitrobenzene
Synonyms:
p-chloronitrobenzene
Group of substances:
organic
Physical appearance:
monoclinic crystals
Empirical formula (Hill's system for organic substances):
C
6
H
4
ClNO
2
Molar/atomic mass: 157.554
Melting point (°C):
82.2
Boiling point (°C):
238
Solubility (g/100 g of solvent):
carbon disulphide
: soluble [
Ref.
]
chloroform
: soluble [
Ref.
]
diethyl ether
: soluble [
Ref.
]
ethanol
: sparingly soluble [
Ref.
]
water
: insoluble [
Ref.
]
Density:
1.2979 (90°C, g/cm
3
)
Reactions of synthesis:
Yeild 68%. [
Ref.1
,
Ref.2
]
C
6
H
5
Cl + HNO
3
→ ClC
6
H
4
NO
2
+ H
2
O
Yeild 55%. [
Ref.1
,
Ref.2
]
C
6
H
5
Cl + HNO
3
→ ClC
6
H
4
NO
2
+ H
2
O
Reactions:
Yeild 80-82%. [
Ref.1
,
Ref.2
]
O
2
NC
6
H
4
Cl + C
6
H
5
OK → O
2
NC
6
H
4
OC
6
H
5
+ KCl
Yeild 82%. [
Ref.1
]
O
2
NC
6
H
4
Cl + KF → O
2
NC
6
H
4
F + KCl
Refractive index (n
D
):
1.5376 (100°C)
References:
CRC Handbook of Chemistry and Physics. - 95ed. - CRC Press, 2014. - pp. 3-114
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© Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru