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Properties of substance:
trifluoromethyl hypochlorite
Group of substances:
organic
Empirical formula (Hill's system for organic substances):
CClF
3
O
Structural formula as text:
CF3OCl
Molar/atomic mass: 120.458
Melting point (°C):
-142
Boiling point (°C):
-46
Decomposition temperature (°C):
165
Numerical data:
Year of discovery: 1968
Reactions of synthesis:
[
Ref.1
]
COF
2
+ ClF → CF
3
OCl
Reactions:
Yeild 91%. [
Ref.1
]
2CF
3
OCl → CF
3
OOCF
3
+ Cl
2
[
Ref.1
]
(CH
3
)
4
NCl + CF
3
OCl → (CH
3
)
4
NOCF
3
+ Cl
2
References:
Journal of the American Chemical Society. - 1969. - Vol. 91, No. 11. - pp. 2903
Journal of the American Chemical Society. - 1969. - Vol. 91, No. 6. - pp. 1311
Некрасов Б.В. Основы общей химии. - Т.1. - М.: Химия, 1973. - pp. 530 [Russian]
Успехи химии. - 1980. - Т.49, №7. - pp. 1270 [Russian]
Химическая энциклопедия. - Т. 1. - М.: Советская энциклопедия, 1988. - pp. 573 [Russian]
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© Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru