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Properties of substance:
ethyl perchlorate
Group of substances:
organic
Physical appearance:
colorless liquid
Empirical formula (Hill's system for organic substances):
C
2
H
5
ClO
4
Structural formula as text:
CH3CH2OClO3
Molar/atomic mass: 128.51
Boiling point (°C):
89
Solubility (g/100 g of solvent):
ethanol
: soluble [
Ref.
]
water
: insoluble [
Ref.
]
Numerical data:
Year of discovery: 1841
Reactions of synthesis:
Yeild 47%. [
Ref.1
]
C
2
H
5
OC(O)Cl + AgClO
4
→ C
2
H
5
OClO
3
+ AgCl + CO
2
Yeild 56%. [
Ref.1
,
Ref.2
]
C
2
H
5
OH + Cl
2
O
7
→ C
2
H
5
OClO
3
+ HClO
4
[
Ref.1
]
(C
2
H
5
OSO
3
)
2
Ba + Ba(ClO
4
)
2
→ 2C
2
H
5
OClO
3
+ 2BaSO
4
[
Ref.1
]
3H
2
NCOOC
2
H
5
+ Cl
2
O
7
→ C
2
H
5
OClO
3
+ [H
2
NC(OH)OC
2
H
5
]ClO
4
+ H
2
NCONHCOOC
2
H
5
References:
Encyclopedia of explosives and related items. - Vol. 6. - New Jersey, 1974. - pp. E316
Urbanski T. Chemistry and technology of explosives. - vol.2. - Warszawa, 1965. - pp. 447-448
Успехи химии. - 1988. - Т.57, №11. - pp. 1815-1839 [Russian]
Химическая энциклопедия. - Т. 3. - М.: Советская энциклопедия, 1992. - pp. 499 [Russian]
Шумахер И. Перхлораты: свойства, производство и применение. - М.: ГНТИХЛ, 1963. - pp. 85 [Russian]
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© Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru